<jats:title>Abstract</jats:title><jats:p>Further innovation in the field of selective laser sintering (SLS) is strongly connected to the availability of new materials since the market is dominated by polyamide 12 (&gt;90%). The aim of this publication is to develop a descriptive model for the droplet formation process in a Filament Extension Atomizer to predict the applicability to exploit further polymers for the SLS process. The feasibility was tested, investigated and characterized using a “Dripping out of a nozzle” setup for uniaxial extension. The droplet formation process was then observed via high-speed camera imaging and classified for certain parameters. The experiments were carried out using semi-diluted polyethylene oxide (600–4000 kg/mol), glycerol and water solutions as model fluids. Driven by the Plateau-Rayleigh instability, different types of spherical droplets were observed and various droplet formation mechanisms demonstrated and analyzed. Based on the experimental results, a predictive model is derived to describe various essential parameters.</jats:p>